4000-520-616
欢迎来到免疫在线!(蚂蚁淘生物旗下平台)  请登录 |  免费注册 |  询价篮
主营:主营:Sigma生化试剂,Millipore密理博抗体、生命科学及高性能材料等等
咨询热线电话
4000-520-616
当前位置: 首页 > 产品中心 > Other_biological_dyes > Sigma-Aldrich/Tricyclohexylphosphine tetrafluoroborate/631493-1G/1G
商品详细Sigma-Aldrich/Tricyclohexylphosphine tetrafluoroborate/631493-1G/1G
Sigma-Aldrich/Tricyclohexylphosphine tetrafluoroborate/631493-1G/1G
Sigma-Aldrich/Tricyclohexylphosphine tetrafluoroborate/631493-1G/1G
商品编号: 631493-1G
品牌: Sigma
市场价: ¥393.97
美元价: 303.05
产地: 美国(厂家直采)
公司:
产品分类: 其他生物染料
公司分类: Other_biological_dyes
联系Q Q: 3392242852
电话号码: 4000-520-616
电子邮箱: info@ebiomall.com
商品介绍
  • CAS Number 58656-04-5

  • Linear Formula (C6H11)3P · HBF4

  • Molecular Weight 368.24

  •  MDL number MFCD03840580

  •  PubChem Substance ID 24882425

  • Popular Documents:  Datasheet (PDF)  

Properties:

Related Categories Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds,
More...
InChI Key   MYSMMEUXKHJYKH-UHFFFAOYSA-O
assay   97%
mp   164 °C(lit.)
ligand for   Arylations
  Sonogashira Coupling
  Stille Coupling
  Suzuki-Miyaura Coupling

Description:

Packaging

1, 5 g in glass bottle

Application

Tricyclohexylphosphine tetrafluoroborate may be used in the following processes:
• As a ligand for preparing C-homoaporphine alkaloids via microwave-assisted direct-arylation.
• To synthesize poly-[9,9-bis(3-propylamide-2-methylpropyl sulfonic acid) fluorene]-co-(4,4′-diphenyl) (PFDBSO3H), which can be employed as a template and doping agent for enhancing the conductivity of poly(3,4-ethylenedioxythiophene) (PEDOT) films.
• To improve the reactivity of palladium-catalyzed Suzuki-Miyaura cross-coupling reaction between MIDA boronates and less activated alkenyl tosylates.

Used with Ru(cod)Cl dimer to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.

General description

Tricyclohexylphosphine tetrafluoroborate (PCy3·HBF4) is an inexpensive and air-stable phosphine ligand, commonly used in cross-coupling reactions.

Safety:

Personal Protective Equipment 
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RIDADR 
NONH for all modes of transport
WGK Germany 
3
品牌介绍
      西格玛奥德里奇(Sigma-Aldrich)是一家在生命科学领域有着领导地位且拥有高科技产品的公司。西格玛奥德里奇(Sigma-Aldrich)根据研发与实验室用户的实际用途,旗下品牌包括Sigma®、Aldrich®、Fluka® 和 Supelco®,分别对应于生命科学、化学、分析和色谱领域的产品。 Vetec™ 为Sigma-Aldrich 旗下新成员,以极具亲和力的本地价格为用户提供质量可靠的常用生化和化学产品。Sigma-Aldrich 家族另一成员SAFC则是全球10大精细化工公司之一,提供全球领先的特殊化学品与生物制品。  Sigma-Aldrich为实验室研究提供上千种耗材产品,在化学和生物领域提供特殊的产品和支持,是众多研发人员日常的放心选择。公司已推出高品质的Sigma®细胞培养类耗材,并携手BRAND、Greiner、Corning和Axygen提供卓越服务。